Campus Consortium for Environmental Excellence


R&D Air Emissions

Project XL
Final Rule

2001 Progress
2002 Progress

Final Project Agreement
Final Agreement
XL Stakeholders
Leighton Letter
Regulatory Relief
XL Rule

Legal Aspects
RCRA and Labs
LSEM RCRA interp
Minimizing Costs
Current Reg Arena
UConn RCRA Workshop
Yale RCRA Inspection
UVM XL Info
Development of a Laboratory EMP
Glassware Waste Project
Waste Min Project
Contacts and Info
RCRA
LabWAM Priorities and Accomplishments
Background Information

Fixing RCRA (Powerpoint)
Chemical Safety Levels
Kids in Labs (Powerpoint)
California
Colorado

Enforcement
Region 1
Region 2

Region 3
The R&D NESHAP Development Process
Clean Air Act

Pilot Schools' Draft EMP's

EPA Midterm Report

Boston College
BC Plan
BC Standards
UMASS Boston
EMP
Environmental Management Standard
University of Vermont
EMP
Lab Workers' FAQ's
The Rule, UVM docs
Baseline Report
Informatics Green Bridge Websites LabXL Home

Table 1. Summary Information for Selected Research and Development Facilities[1]

Chemical Industry Facilities

Company Location Collocated R&D Controls R&D HAP Emissions Facility-wide HAP Emissions Basis for Emission Estimates Source of Information Comments
Albemarle Baton Rouge, LA no [2] scrubbers[3]
condensers
flares
0.6 tpy HAP[4] actual (1996) Toxics Emissions Data Inventory (TEDI) Facility & State Albemarle also operates a bromine terminal at this site. Located on same contiguous property with Ethyl Corporation, which is separately owned and permitted.
Cerac, Inc. Milwaukee, WI yes information unavailable Facility:
2.07 tpy HAP actual (1994)

State:
13.7 tpy HAP actual

State emissions inventory information Facility & State Speciated HAP information provided by State.

Facility stated that HAPs emitted include arsenic, cadmium, chromium, chlorine, hydrogen chloride, and hydrogen sulfide.

DuPont Deepwater, NJ yes thermal oxidizer
scrubbers (multi-stage packed tower, spray tower absorber)
carbon adsorber
condensers (dry ice; chilled, building, or process water)
filters
Facility:
0.566 tpy VOC[5] actual
(a pilot plant w/ both R&D and manufacturing)
0.033 tpy (652 lb/yr) HAP actual
(a pilot plant w/ both R&D and manufacturing)
Facility:
500 tpy VOC actual (facility, incl. mfg.)
70 to 80 tpy HAP actual
(facility, incl. mfg.)
State:

110.8 tpy (221,620 lb/y) stack
238 tpy (476,085 lb/y) fugitive

Emissions inventory

Toxic Release Inventory (TRI) emissions calcs based on chemical use
Plantsite HAP emissions from state TRI

Facility & State
Polaroid Waltham, MA yes afterburner

(on research test coater)

0.57 tpy organic solvents actual (1995)
0.79 tpy organic solvents actual (1996)
Emissions calculations Facility
Polaroid Cambridge, MA no information unavailable 10.96 tpy VOC actual (1996)

5.0 tpy HAP actual

(1996)

Emissions calculations Facility Permit limits are 40 tpy VOC/HOC[6] and 25 tpy HAPs.
Solutia

Springfield, MA yes industrial hygiene controls:condensers
hoods
mist eliminators
1.6 tpy actual VOC
(pilot plants) (1996)
<1.5 tpy actual VOC (laboratories)
Emissions estimate Facility
Specialty Chemical Products Marinette, WI yes condensers (as a part of the process line)

four scrubbers (as add-on controls)

Facility:
16 tpy total (VOC & HAP) actual (1997, est.)
State:
< 1 tpy VOC actual (1995)
zero (or below reporting levels) HAP (1995)
7.9 tpy HAP actual (unknown year)
Facility and State emissions inventory information Facility & State Speciated HAP information provided by State.

R&D and general operations not separated. Pilot plant used for regular operations, and R&D a very small portion of current work.

Largest emission HAP is mixed xylenes at approximately 3 tpy (1997, est.)

Facility is investigating difference between State and facility emissions estimates.

Union Carbide

(chemicals)

Bound Brook, NJ no information unavailable 9.85 tpy actual VOC (1996)

(4.93 tons R&D, remainder from a boiler)

Lab hood emissions factor for NJ Facility The PTE[7] for lab hoods was 5 tpy assuming 16 hours per day operation. Permitted for pilot plants.
Union Carbide South Charleston, WV no information unavailable 4.5 tpy HAP actual (1996)

95 tpy VOC actual (1996)

State emissions statement Facility 35% of HAP emissions fugitive;

65% of HAP pilot plants and lab hoods.

State permit includes speciated HAP emissions.

Good management practices used to reduce emissions.

>100 tpy PTE VOC for R&D

Vulcan Wichita, KS yes information unavailable 0.23 tpy (454 lb/yr) VOC actual (current) (pilot plant)
0.5 tpy (1008 lb/yr) VOC actual (future) (pilot plant)
0.22 tpy (439 lb/yr) HAP actual (current) (pilot plant)
0.44 tpy (878 lb/yr) HAP actual (future) (pilot plant)
Emissions calculations Facility Collocated with manufacturing operations, but manufacturing operation emissions were reported to be 1.38 tpy (2759 lb/yr) and 98% controlled.

Government Facilities

Company Facility Location Collocated R&D Controls R&D HAP Emissions Facility-wide HAP Emissions Basis for Emission Estimates Source of

Information

Comments
Department of Defense[8] - Naval Surface Warfare Center Indian Head, MD Yes none on most equipment; some carbon adsorbers and HEPA filters on pilot plant buildings <1 tpy Material balance, R&D emissions were assumed to be 1% of the amount used in the pilot plants. Facility Lab emissions were not calculated.
Department of Defense - Naval Surface Warfare Center Carderock, MD No none <1 tpy Varies, most taken from AP-42 Facility
Department of Defense - Naval Underwater Warfare Center Newport, RI No afterburner on the torpedo engine test stand 1.2 tpy Estimated emissions Facility
Department of Defense - Naval Surface Warfare Center Panama City, FL No particulate filter on paint booth VOC- 0.59 tpy

nonVOC - 6.0E-5 tpy

AP-42, material balance Facility
Department of Defense - Naval Air Warfare Center Patuxent River, MD Yes none on engine test cells 0.7658 tpy Estimated emissions Facility
Department of Defense - Naval Air Warfare Center China Lake, CA Yes none Available June 98 Various, doing a comprehensive evaluation Facility
Department of Defense - Naval Submarine Medical Research Laboratory Groton, CT Yes none < 0.005 tpy (<10 lb/yr) (acetonitrile) Best engineering judgment Facility
Department of Defense - Detachment Naval Medical Research Institute Bethesda, Brooks AFB TX No none <0.01 tpy (<20 lb/yr) (methanol, ethylene glycol) Best engineering judgment Facility
Department of Defense - Naval Facilities Engineering Services Center Port Hueneme, CA No none < 0.03 tpy
(Many different HAPs in small amounts, largest are: Methyl Chloroform, MEK, Methyl Chloroform, Formaldehyde, Toluene, Methanol, PCE, Xylene, 20 others)
AP-42, material balance, permit limits Facility
Department of Defense - Naval Medical Research Institute Bethesda, MD No information unavailable 1.25 tpy
Majority of HAP emissions (facility-wide) are Toluene, Ethylene Oxide, Xylenes, Benzene, o-Xylene, Ethyl Benzene, and Formaldehyde. (Xylene is used to fix tissue to slides.)
2.5 tpy HAP facility-wide Estimating 50% from Hospital, 50% from R&D facility. Facility
Department of Defense - U.S. Army Armament Research, Development & Engineering Center Picatinny Arsenal, NJ No none A few pounds/year Best engineering judgment Facility
Department of Defense - Aberdeen Proving Ground Edgewood, MD Yes information unavailable 5.3 tpy Material balance Facility
Department of Defense - Yuma Proving Ground Yuma, AZ Yes none Hydrofluoric Acid 2 gals/yr AP-42 Facility
Department of Defense - Detroit Arsenal Detroit, MI No none 0.004 tpy

Benzene, Toluene, Xylene, 1,3 Butadiene, Formaldehyde, Acetaldehyde, Methyl Chloroform

AP-42 Facility
Department of Defense - Rock Island Arsenal Rock Island, IL Yes none 0.134 tpy (267.2 lb/yr)

Petroleum Ether (not calculated from oil testing)

AP-42 Facility
Department of Defense - Soldier Systems Command Natick, MA No a few lab hoods are equipped with activated carbon filters; a few other are equipped with "dry ice traps" (simple condensors) 0.003 tpy
Acetonitrile, Aniline, Benzene, Benzyl Chloride, Carbon Tetrachloride, Chloroform
AP-42 Facility
Department of Defense - Fort Monmouth, NJ NJ No none Methylene Chloride, Chloroform, Xylene, Toluene AP-42 Facility
Department of Defense - Edwards AFB CA Yes none 3 tpy Material balance and best engineering judgment Facility
Department of Defense - Eglin AFB FL Yes none 0.02 tpy Material balance and best engineering judgment Facility
Department of Defense - Brooks AFB TX No information unavailable < 0.1 tpy Material balance and best engineering judgment Facility
Department of Defense - Arnold AFB TN Yes none 0.1425 tpy Material balance and best engineering judgment Facility
Department of Defense - Kirtland AFB NM Yes none 0.055 tpy Material balance and best engineering judgment Facility
Department of Defense - Holloman AFB NM Yes none < 1 tpy Material balance and best engineering judgment Facility
Department of Defense - Wright-Patterson AFB OH Yes none 1.6 tpy Material balance and best engineering judgment Facility
Department of Defense - Rome Laboratory NY No none < 0.05 tpy Material balance and best engineering judgment Facility
Department of Energy - Grand Junction Project Office Grand Junction, CO no scrubbers 0.3 to 0.4 tpy HAP actual Emissions Estimate Facility Facility stated that actual emissions are much less than the permit level of 11 tpy HAP (methylene chloride), and the operations at this location are being phased out.
Department of Energy[9] - Oak Ridge National Laboratory Oak Ridge, TN unknown information unavailable 13.3 tpy HAP actual (1994)
12.7 tpy HAP actual (1995)
11.4 tpy HAP actual (1996)
12.5 tpy HAP actual (avg.)
Mass balance using chemical procurement records and laboratory personnel input Facility